Product ID:G-335C INDUSTRIAL X-RAY FIXER PART B
MSDS Date:03/26/1998
FSC:6750
NIIN:01-461-5240
Status Code:A
Kit Part:Y
MSDS Number: CLPHC

AGFA CORPORATION

100 CHALLENGER RD
RIDGEFIELD PARK, NJ 07660
US

Emergency Phone: 303-623-5716 HEALTH

Info Phone: 201-440-2500

Preparer: R. RUPPEL-KERR

Cage: 1MVW0

AGFA DIVISION, BAYER CORPORATION

RIDGEFIELD PARK, NJ 07660 US

Telephone: 201-440-2500

Cage: 0P7P7

ALUMINUM SULFATE

CAS: 10043-01-3

RTECS: BD1700000

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETIC ACID

CAS: 64-19-7

RTECS: AF1225000

OSHA PEL 25 MG/M3;10 PPM

ACGIH TLV: 25 MG/M3;10 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SULFURIC ACID

CAS: 7664-93-9

RTECS: WS5600000

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

OXALIC ACID

CAS: 144-62-7

RTECS: RO2450000

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

LD50 LC50 Mixture:ORAL LD50 IS 3310 MG/KG (RAT)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION-OVEREXPOSURE CAN
CAUSE IRRITATION TO THE RESPIRATORY TRACT. SKIN-DIRECT CONTACT CAN
CAUSE SKIN IRRITATION, POSSIBLY SEVERE. EYE-OVEREXPOSURE CAN CAUSE
SEVERE IRRITATION. INGESTION-SW ALLOWING CONCENTRATED ACETIC ACID
MAY CAUSE SEVERE INJURY. INGESTION OF ALUMINUM SULFATE MAY CAUSE
IRRITATION OR BURN THE DIGESTIVE TRACT. IF INGESTED, SULFURIC ACID
& OXALIC ACID ARE CORROSIVE TO THE TISSUES WITH WHICH THEY COME IN
CONTACT. CHRONIC: INHALATION-KIDNEY DAMAGE. SKIN-SKIN DESICATION &
ULCERATION. EYE-LACRIMATION & CHRONIC CONJUNCTIVITIS. INGESTION-MAY
CAUSE KIDNEY DAMAGE.
Explanation of Carcinogenicity:THE COMPONENTS OF THIS PRODUCT ARE NOT
LISTED BY NTP, IARC OR REGULATED AS A CARCINOGEN BY OSHA.
Effects of Overexposure:INHALATION-COUGHING, RUNNY NOSE & SORE THROAT,
IRRITATING TO THE MUCOUS MEMBRANES OF THE RESPIRATORY TRACT.
CHOKING & INFLAMMATION OF THE RESPIRATORY TRACT. SKIN-BURNING,
REDDENING, ITCHING & SWELLING . SEVERE BURNS & BLISTERING OF THE
SKIN. EYE-BURNING, STINGING, REDDENING, TEARING, SWELLING &
POSSIBLE INJURY TO THE CORNEA DEPENDING ON THE CONCENTRATION OF THE
ACID. PERMANENT EYE DAMAGE INCLUDING BLINDNESS MAY RESULT.
INGESTION-MAY CAUSE BURNING PAIN IN THE MOUTH, THROAT, ESOPHAGUS &
ABDOMEN.
Medical Cond Aggravated by Exposure:PERSONS WITH PREEXISTING EYE, SKIN,
KIDNEY, OR RESPIRATORY TRACT DISORDERS MAY BE MORE SUSCEPTIBLE TO
THE EFFECTS OF THIS PRODUCT.

First Aid:EYES: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY
OF WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN. SKIN: IN CASE
OF CONTACT, REMOVE CONTAMINATED CLOTHING, IMMEDIATELY WASH SKIN
WITH PLEN TY OF WATER. WASH CLOTHING BEFORE REUSE. CALL A PHYSICIAN
IF IRRITATION PERSISTS. INHALATION: IF INHALED, REMOVE TO FRESH
AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. INGESTION: DO NOT INDUCE
VOMITING. DRINK 1 - 2 GLASSES OF WATER. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. SEEK MEDICAL ATTENTION. TAKE THIS
MSDS TO PHYSIC IAN.

Flash Point:NONCOMBUSTIBLE
Extinguishing Media:MATERIAL IS NOT COMBUSTIBLE. USE EXTINGUISHING
MEDIA SUITABLE FOR OTHER COMBUSTIBLE MATERIALS IN THE AREA.
Fire Fighting Procedures:EVACUATE PERSONNEL TO A SAFE AREA. KEEP
PERSONNEL REMOVED AND UPWIND OF FIRE. WEAR SELF-CONTAINED BREATHING
APPARATUS.
Unusual Fire/Explosion Hazard:WHEN HEATED TO DECOMPOSITION EMISSION OF
TOXIC FUMES OF S02 IS POSSIBLE.

Spill Release Procedures:USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT
DURING CLEAN UP. DIKE SPILL. PREVENT LIQUID FROM ENTERING SEWERS,
WATERWAYS OR LOW AREAS. SOAK UP WITH SAWDUST, SAND, OIL DRY OR
OTHER ABSORBENT MATERIAL. SPILL MAY BE NEUTRALIZED WITH POWDERED
SODIUM CARBONATE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE BETWEEN 40F (4.4C) AND 80F (
26C). PREFERRED STORAGE IS AT 68F (20C). KEEP FROM FREEZING. AVOID
EYE AND SKIN CONTACT, AND STORE IN WELL-VENTILATED AREA. KEEP
CONTAINER TIGHTLY CLOSED. DO NOT STO RE WITH INCOMPATIBLE
MATERIALS.
Other Precautions:DO NOT STORE OR CONSUME FOOD, DRINK, OR TOBACCO IN
AREA WHERE THEY MAY BECOME CONTAMINATED WITH THIS MATERIAL. KEEP
OUT OF THE REACH OF CHILDREN.

Respiratory Protection:UNDER NORMAL CONDITIONS OF USE, RESPIRATOR
PROTECTION IS NOT REQUIRED. IF RESPIRATORS ARE USED, INSTITUTE A
PROGRAM IN ACCORDANCE WITH OSHA STANDARD 20 CFR 1010.134.
Ventilation:USE SUFFICIENT GENERAL ROOM VENTILATION AND/OR LOCAL
EXHAUST TO MAINTAIN AIRBORNE LEVELS OF VAPORS BELOW APPLICABLE
EXPOSURE LIMITS.
Protective Gloves:FOR SKIN PROTECTION USE CHEMICAL RESISTANT GLOVES AND
APRONS.
Eye Protection:SPLASH PROTECTION REQUIRED FOR EYES, EYE GLASSES WITH
SIDE SHIELDS OR GOGGLES.
Other Protective Equipment:FOR SKIN PROTECTION USE CHEMICAL RESISTANT
APRONS. EMERGENCY SHOWERS AND EYE WASH STATIONS SHOULD BE MADE
AVAILABLE. EDUCATE AND TRAIN EMPLOYEES IN THE SAFE USE AND HANDLING
OF THIS PRODUCT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
****UNIT OF ISSUE CONTAINS 2 SETS OF G335C FIXER/ REPLENISHER, PART A/B
2X5 QT; EACH SET CONTAINS (1) PART A (5 QUART BOTTLE), (1) PART B
(1 QUART BOTTLE).****

HCC:C1
Boiling Pt:=100.C, 212.F
B.P. Text:APPROX.
Spec Gravity:APPROX 1.15
pH:< 0.5
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR COLORLESS LIQUID; STRONG VINEGAR ODOR.
Percent Volatiles by Volume:N/E

Stability Indicator/Materials to Avoid:YES
STRONG ALKALI, OXIDIZERS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:CO, CO2, OXIDES OF SULFUR AND OTHER
POTENTIALLY TOXIC FUMES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:RECOVER NONUSABLE FREE LIQUID AND/OR
CONTAMINATED WATER, AND DISPOSE OF IN AN APPROVED AND PERMITTED
TREATMENT SYSTEM. REMOVE NONUSABLE SOLID MATERIAL AND/OR
CONTAMINATED SOIL, FOR DISPOSAL IN AN APPR OVED AND PERMITTED
LANDFILL. DISCHARGE TO SEWER MAY REQUIRE APPROVAL OF PERMITTING
AUTHORITY AND MAY REQUIRE PRETREATMENT.

Toxicological Information:ACUTE TOXICITY: ORAL LD50-3310 MG/KG (RAT).
DERMAL LD50-1060 MG/KG (RABBIT) INHALATION LC50-5620 PPM/1 HR.
(MOUSE). EYE EFFECTS-CORROSIVE. SKIN EFFECTS-CORROSIVE. TOXICITY
DATA FOR: ALUMINUM SULFATE. MUTAGENICITY-POSITIVE MUTAGENICITY
STUDIES IN BACTERIAL AND MAMMALIAN CELL ASSAY SYSTEM.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO ECOLOGICAL INFORMATION AVAILABLE.

Transport Information:TECHNICAL SHIPPING NAME: SULFURIC ACID, ACETIC
ACID. PRODUCT LABEL: G-335C INDUSTRIAL X-RAY FIXER PART B. DOT
DOMESTIC SURFACE). PROPER SHIPPING NAME: CORROSIVE LIQUID, N.O.S.
HAZARD CLASS OR DIVIS ION: 8. UN/NA NUMBER: UN1760. PACKAGING
GROUP: PGII. DOT PRODUCT RQ LBS: NONE. HAZARD LABEL: CORROSIVE.
HAZARD PLACARD: CORROSIVE. LIMITED QUANTITY EXECPTION MAY APPLY TO
THIS PRODUCT, FOR "INNER PACK AGINGS NOT OVER 1L FOR LIQUIDS & 1 KG
FOR SOLIDS. EACH PACKAGE MUST CONFORM TO THE APCKAGING REQUIREMENTS
OF SUBPART B OF PART 173 & NOT EXCEED 30 KG.

SARA Title III Information:SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES:
SULFURIC ACID, (1-5%). SECTION 311/312 HAZARD CATEGORIES: IMMEDIATE
HEALTH HAZARD; DELAYED HEALTH HAZARD. SECTION 313 TOXIC CHEMICALS:
SULFURIC ACID (1-5%). RCRA STATUS: WHEN DISCARDED IN ITS PURCHASED
FORM, THIS PRODUCT MEETS THE FRITERIA OF CORROSITIVITY, AND SHOULD
BE MANAGED AS A HAZARDOUS WASTE (EPA HAZRDOUS WASTE NUMBER D002).
Federal Regulatory Information:OSHA STATUS: THIS PRODUCT IS HAZARDOUS
UNDER THE CRITERIA OF THE FEDERAL OSHA HAZARD COMMUNICATION
STANDARD 29 CFR 1910.1200. TSCA STATUS: ON TSCA INVENTORY. CERCLA:
ACETIC ACID-5,000 LBS; SULFURIC AC ID-1,000 LBS; ALUMINUM
SULFATE-5,000 LBS.
State Regulatory Information:ALUMINUM SULFATE, 5-10%, PENNSLYVANIA
HAZARDOUS SUBSTANCE LIST. PENNSYLVANIA ENVIRONMENTAL HAZARDOUS
SUBSTANCE LIST, MASSACHUSETTS HAZARDOUS LIST, NEW JERSEY HAZARDOUS
SUBSTANCE LIST. WATER, 80-85%, P ENNSYLVANIA NON-HAZARDOUS PRESENT
AT 3% OR GREATER, NEW JERSEY OTHER - INCLUDED IN 5 PREDOMINANT
INGREDIENTS >1%. ACETIC ACID, 1-5%, PENNSYLVANIA NON-HAZARDOUS
PRESENT AT 3% OR GREATER, NEW JERSEY O THER - INCLUDED IN 5
PREDOMINANT INGREDIENTS >1, MASSACHUSETTES HAZARDOUS SUBSTANCE
LIST.